Научный журнал «Вестник Череповецкого государственного университета»
Статья
Полный текст:
Целью данного исследования является изучение термических свойств различных типов биотоплива, анализ компонентов, образующихся в процессе его термического разложения при определенных температурах методом газовой хроматографии. Подготовленные образцы биотоплива помещались в газовый хроматомасс спектрометр GC-MS QP2010Plus, оснащенный системой пиролиза EGA/PY-3030D с использованием программного обеспечения GCMS Solution 2.72. В процессе термического разложения полученные компоненты улавливались в азотной ловушке и последовательно анализировались. В результате проведен газохроматографический анализ разных видов биотоплива: сосна, ель, пеллеты из ели.
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Ischia, M. Pyrolysis study of sewage sludge by TG–MS and TG–GC–MS coupled analyses / [M. Ischia et al.] // J Therm Anal Calorim. – 2007. – Р. 567–574.
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Meszaros, E. Thermogravimetry/ mass spectrometry analysis of energy crops / [E. Meszaros et al.] // J Theem Anal Calorim. – 2007. – Р. 567–574.
Milne, T. A. A review of the chemical composition of fast–pyrolysis oils from biomass / [T. A. Milne et al.] // Bridgwater AV, Boocock DGB, editors. Developments in thermochemical biomass conversion. Vol. 1. – London, 1997. – P. 409–424.
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Mullens, J. The determination of the gases released during heating of a flame retardant for polymers / [J. Mullens et al.] // J Therm Anal Calorim. – 2001. – Р. 669–685.
Ogi, T. Gasification of woody and herbaceous biomass in a small–scale entrained gasifier: comparison of Japanese cedar and Italian ryegrass / T. Ogi, M. Nakanashi, S. Inoue // Science in thermal and chemical biomass conversion. – 2005. – Vol. 1. – P. 620–630.
Ogi, T. Effects of woody biomass variety on gasification in an entrained gasifier / [T. Ogi et al] // Proceedings of IAWPS2005. – 2005. – Vol. 2. – P. 257–258.
Ogi, T. Gasification of biomass in a small-scale entrained gasifier: gasification of Japanese cedar and Italian ryegrass / T. Ogi, M. Nakanashi, S. Inoue // Proceeding of the 8th Japan–China symposium on coal and C1 chemistry. – 2003. – Vol. 1. – P. 227–228.
Ogi, T. Gasification of empty fruit bunch and bagasse using an entrained–flow mode reactor / T. Ogi, M. Nakanashi, Y. Fukuda // J Jpn Inst Energy. – 2011. – Р. 886–894.
Ogi, T. Gasification of Japanese cedar (cryptomeria japonica) bark in an entrained gasifier / T. Ogi, M. Nakanashi // Renew Energy. – 2006. – Р. 1050–1054.
Ogi, T. Thermogravimetric analysis with gas chromatograph mass spectrometry of Japanese fir wood (Abies sacha-linesis) in helium with or without steam–oxygen / T. Ogi, M. Nakanashi, Y. Fukuda // J Therm Anal Calorim. – 2013. –
Р. 929–937.
Onishi, A. TG-MS characterization of pig bone in an inert atmosphere / [A. Onishi et al.] // J Therm Anal Calorim.– 2007. – Р. 405–409.
Pappa, A. TG-MS analysis for studying the effects of the retardants on the pyrolysis of pine–needled and their components / [A. Pappa et al.] // J Therm Anal Calorim. – 2006. – Р. 655–661.
Pasa, VMD. Wood tar pitch: analysis and conceptual model of its structure / VMD. Pasa, F. Carazza, C. Otani // Bridgwater AV, Boocock DGB, editors. Developments in thermochemical biomass conversion. Vol. 1. – London, 1997. – P. 448–61.
Rajkumar, T. Thermal degradation studies on PMMA– HET acid based oligoesters blends / [T. Rajkumar et al.] // J Therm Anal Calorim. – 2010. – Р. 651–660.
Renata, M. Braga Characterization and comparative study of pyrolysis kinetics of the rice husk and the elephant grass / [M. Braga Renata et al.] // J. Thermal Anal. Calorimetry. – 2013. – №11. – doi 10.1007/s10973–013–3503.
Shimasaki, C. Pyrolysis and mass spectra of trimeryl- silyl derivatives of monosaccharides / [C. Shimasaki et al.] // J Therm Anal Calorim. – 1995. – Р. 855–867.
URL: Mass_Spec/GCMS–QP2010_Plus_F.pdf.
Wehlte, S. The impact of wood preservatives on the flash pyrolisis of biomass / [S. Wehlte et al.] // Bridgwater AV, Boocock DGB, editors. Developments in thermochemical biomass conversion. Vol. 1. – London, 1997. – P. 206–219.
Xie, W. Thermal characterization of materials using evolved gas analysis / W. Xie, Wp. Pan // J Therm Anal Calorim. – 2001. – Р. 669–685.
Ключевые слова:
древесная биомасса, газовая хроматография, хроматограмма, пиролиз, термическое разложение, компоненты
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